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With the increasing attention for green ...
A Ce-catalyzed strategy is developed to ...
A novel oxidative deoximation method was...
The 4, 4 ’ difluorobenzophenone and the ...
4,4'-difluorobenzhydryl alcohol
cyclohexanone
hexahydro-2H-oxepin-2-one
4,4'-Difluorobenzophenone
Conditions | Yield |
---|---|
4,4'-difluorobenzhydryl alcohol; cyclohexanone; With N-hydroxyphthalimide; 2,2'-azobis(isobutyronitrile); oxygen; In ethyl acetate; at 75 ℃; for 22h;
With ammonium cerium (IV) nitrate; 1,1,1,3',3',3'-hexafluoro-propanol; In ethyl acetate; at 45 ℃; for 10h;
|
bis(methanesulfonyl)peroxide
4,4'-difluorodiphenylmethane
4,4'-difluorobenzhydryl alcohol
4,4'-Difluorobenzophenone
Conditions | Yield |
---|---|
bis(methanesulfonyl)peroxide; 4,4'-difluorodiphenylmethane; With trimethylsilyl acetate; copper (I) acetate; In dichloromethane; at 23 ℃; for 12h; Inert atmosphere;
With sodium methylate; In methanol; at 23 ℃; for 8h;
|
34% 9% |
tetrachloromethane
fluorobenzene
phosgene
dichloro-bis-(4-fluoro-phenyl)-methane
1,1,2,2-tetrakis-(4-fluorophenyl)-ethane-1,2-diol
ethyl 3,3-bis(4-fluorophenyl)-3-hydroxypropanoate
1,1-bis-(4-fluoro-phenyl)-ethanol
tris-(4-fluoro-phenyl)-ethene